Avery Ryan and Leroy Jethro Gibbs
First of all, let's just bring up that these two can stare vaguely into the distance like nobody's business. More importantly, Gibbs has no idea how to use any technology made after 2001, so CSI: Cyber's Avery Ryan could definitely be able to help with that. It's a new-school-meets-old-school match made in virtual heaven. It's safe to say, though, they probably wouldn't meet through online dating.
Watch CSI: Cyber Wednesdays at 10/9c and NCIS Tuesdays at 8/7c.